Station: 42

Sub Area: ENP

BioChem Date: 2014-09-05
BioChem Crew: SED/HNJ

Location
Latitude	25.49445902
Longitude	-80.72860908

NOTES: PB collected fom 2nd core. 2 photos of core 1. Double-checked ORP, cleaned sonde cage - still reading higher than usual.

Basic

Item	Value	Description
AIR_DEP	Y	Mercury air deposition water sample field blank site (Y/N)
BIOVOLUME	200	Periphyton within water column (floating and sweaters) harvested from 0.25 square meter quadrat, measured in graduated cylinder, mL
CAMERA_A	S49551	EPA property number of digital camera used for field documentation of habitat and soil core
CAMERA_B	S15996	EPA property number of digital camera used for field documentation of habitat and soil core
CATTAIL	N	Cattail present at the station, based on visual observation, Y/N
CHAMBER	1	EPA unit number for the surface water sampling chamber
CHOPPER	N31AT	number of helicopter and associated sampling equipment and supply cache
COND	447	in situ surface water specific conductance, YSI sonde, umhos/cm
CYCLE	11	sampling cycle number
DEVICE	Q	Device used for biovolume estimate, trash can T (area 0.062 square meters) or quadrat Q (area 0.25 square meters)
DO	3.76	in situ surface water dissolved oxygen, YSI sonde, mg/L
DOCSWEA	11	Dissolved organic carbon in surface water, mg/L (EPA SESD)
DOMINANT_MACRO	sawgrass	Dominant macrophyte at station based on visual observation
DUPE	N	Field duplicate station (Y/N)
FISHNUM	5	number of mosquitofish collected for Hg analysis
FLOC_or_FILM	N	biofilm or floc presence within 0.25 square meter quadrat (Y/N)
FLOCCOLPOR	NONE	Portion of floc collected from core; none, part or all
FLOCCONTB	0	number of storemore bottles used for floc collection
FLOCCONTT	0	number of tubs used for floc collection
FLOW	3	description of surface water flow at sampling site, based on visual observation: 1=sheetflow, 2=isolated pool (no flow), 3=uncertain
GARMIN	S49553	Garmin Global Positioning System EPA property number, used for navigation to the station
GREEN_AL	N	green algae presence in 0.25 square meter quadrat (Y/N)
LOCATION	NOMINAL	sampled within 5 meters of GPS coordinates = nominal; 5-20 meters = shifted; >20 meters = station rejected;
LOGBOOK	3	Field logbook number
OMSDFS	18	organic matter in soil, %, calculated as 100-ASHSDFS % (FIU Soil/Sediment Biogeochemistry Lab)
ORP	164.3	Redox potential from YSI sonde, mV
PB_PERISM	Y	benthic periphyton (soil mat) presence in 0.25 square meter quadrat (Y/N)
PE_PERISW	Y	epiphytic (sweaters) periphyton presence in 0.25 square meter quadrat (Y/N)
PERI	100	Total percent cover of periphyton within 0.25 square meter quadrat, covered by all periphyton (PE, PB, PF) if 3-dimensional quadrat volume was compressed into a 2-dimensional plane
PF_PERIF	N	floating periphyton presence in 0.25 square meter quadrat (Y/N)
pH	7.26	in situ surface water pH, YSI sonde, std units
PILOT	CARLOS LUQUE	Helicopter pilot
PLANT_COLL	N	whole sawgrass plant collected for mercury analysis? (Y/N)
SOILTYPE	8	soil type categories, by visual observation of core: 1=peat, 2=peat layers, 3=marl, 4=marl layers, 5=sand, 6=other, 7=peat over marl, 8=marl over peat, 9=marl+peat mixed
TIME_LANDING	09:15:00	Helicopter landing time at station
TIME_SAMPLE	09:45:00	Water sample collection time
TIME_TAKE_OFF	12:15:00	Helicopter departure time from station
TRIMBLE	A77114	Trimble Global Positioning System EPA property number, used to determine final station coordinates, taken at the centroid of the soil core collection locations
TRIMBLE_FILE_NAME	4090510A	File name logged at the station by the Trimble unit
TRIMBLE_LONG	80.72860908	Longitude, decimal degrees, from Trimble, post-processed
TURB	0.8	in situ surface water turbidity, YSI sonde, NTU
VEGTYPE	2	plant community observed at sampling site: 1=wet prairie, 2=sawgrass marsh, 3=pond/gator hole, 4=cattail, 5=willow, 6=cypress, 7=brush, 8=other, 9=slough
WEATHER	1	weather conditions: 1=clear, 2=slightly overcast, 3=medium overcast, 4=very overcast, 5=drizzle, 6=rain
YSI_DEPTH	4	depth of deployment of probe array in surface water, inches
YSI_ID	18	EPA unit number for the YSI sonde

Item	Value 1	Value 2	Value 3	Average	Units	Description
DEPBEDR	1.4	0.3	1	0.9	FEET	depth to bedrock, point of refusal with metal probe, feet
FLOCTH	0	0	0	0	CM	vertical extent (length) of floc layer in core, cm
PB	2	2	1.5	1.83	CM	field data: benthic periphyton, or cookie, thickness, cm, collected from 3-inch inner diameter clear polycarbonate core
SOILCTH	10	10	10	10	CM	vertical extent (length) of soil sample, from soil surface to bottom of core, centimeters
SOILTHI	1.2	0.1	0.7	0.67	FEET	soil thickness, feet, metal probe to point of refusal, calculated as difference between WATDEPTH and DEPBEDR
WATDEPTH	0.2	0.2	0.3	0.23	FEET	water depth, measured with probe, feet

BioChemistry

Item	Value	Units	Q	Protocol	Description
ASHPBFS	750000	mg/kg		FIU Soil/Sediment Biogeochemistry Laboratory	Ash in dry samples, benthic periphyton, after ashing at 550 C, mg/kg, (FIU Soil/Sediment Biogeochemistry Lab)
ASHPCFS	650000	mg/kg		FIU Soil/Sediment Biogeochemistry Laboratory	Ash in dry samples, composite epiphytic and floating periphyton, after ashing at 550 C, mg/kg, (FIU Soil/Sediment Biogeochemistry Lab)
ASHSDFS	820000	mg/kg		FIU Soil/Sediment Biogeochemistry Laboratory	Ash in dry samples, soil, after ashing at 550 C, mg/kg, (FIU Soil/Sediment Biogeochemistry Lab)
ASHSDFSP	82	%		FIU Soil/Sediment Biogeochemistry Laboratory	Ash in dry samples, soil, after ashing at 550 C, percent, (FIU Soil/Sediment Biogeochemistry Lab)
BDPBFS	0.22	g/cc		FIU Soil/Sediment Biogeochemistry Laboratory	Bulk Density of benthic periphyton, g/cc dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
BDPCFS	0.09	g/cc		FIU Soil/Sediment Biogeochemistry Laboratory	Bulk Density of composite floating and epiphytic periphyton, g/cc dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
BDSDFS	0.42	g/cc		FIU Soil/Sediment Biogeochemistry Laboratory	Bulk Density of soil, g/cc dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
CHLAPBFB	0.032	mg/kg		FIU nutrient analysis laboratory	Chlorophyll a in benthic periphyton, mg/kg, dry weight (FIU Nutrient Analysis Lab)
CHLAPCFB	0.21	mg/kg	A	FIU nutrient analysis laboratory	Chlorophyll a in composite epiphytic and floating periphyton, mg/kg, dry weight (FIU Nutrient Analysis Lab)
CHLASWFB	1.5	ug/L		FIU nutrient analysis laboratory	Chlorophyll a in surface water, ug/L (FIU Nutrient Analysis Lab); MRL= 0.1 ug/L
CHLAVOL	140	ML			volume of surface water filtered for chlorophyll-a analysis, ml
CLSWEA	40	mg/L			Chloride in surface water, mg/L (EPA SESD); MRL=0.1 mg/L
FNH4SWFB	0.013	mg/L	J,Q-2	FIU nutrient analysis laboratory	Filtered Ammonia in surface water, mg/L (FIU Nutrient Analysis Lab); MRL = 0.0031mg/L; PQL = 0.0140 mg/L
FNNSWFB	0.0074	mg/L	J,Q-2	FIU nutrient analysis laboratory	Filtered Nitrite + Nitrate in surface water, mg/L (FIU Nutrient Analysis Lab)
FNO2SWFB	0.0006	mg/L	J,Q-2	FIU nutrient analysis laboratory	Filtered Nitrite in surface water, mg/L (FIU Nutrient Analysis Lab)
FNO3SWFB	0.0068	mg/L	J, CV	FIU nutrient analysis laboratory	Filtered Nitrate in surface water, mg/L (FIU Nutrient Analysis Lab)
H2OPBFS	79	%			Water content of benthic periphyton as percentage of wet weight (FIU Soil/Sediment Biogeochemistry Lab)
H2OPCFS	92	%		FIU Soil/Sediment Biogeochemistry Laboratory	Water content of composite epiphytic and floating periphyton as percentage of wet weight (FIU Soil/Sediment Biogeochemistry Lab)
H2OSDFS	62	%			Water content of soil as percentage of wet weight (FIU Soil/Sediment Biogeochemistry Lab)
H2SBWEE	0.008	mg/L	J		Bottom water sulfide, mg/L, HACH method 8131 (EPA SESD Contractor)
LEAF_COLL	N	Y/N			sawgrass leaves collected for carbon, nitrogen and phosphorus analysis (Y/N)
MEHGPBFC	0.89	ng/g		FIU mercury analytical laboratory	Methyl Mercury in benthic periphyton, ng/g (FIU Mercury Lab)
MEHGPCFC	0.31	ng/g		FIU mercury analytical laboratory	Methyl Mercury in composite epiphytic and floating periphyton, ng/g (FIU Mercury Lab)
MEHGSDFC	0.3	ng/g		FIU mercury analytical laboratory	Methyl Mercury in soil, ng/g (FIU Mercury Lab); 2014 MDL=0.04 ng/g; MRL= 0.12 ng/g; results reported as dry weight
MEHGSWFC	0.094	ng/L	U,B-4	FIU mercury analytical laboratory	Methyl Mercury in surface water, ng/L (FIU Mercury Lab); MDL=0.02 ng/L; PQL=0.06 ng/L
ORPDEPTH	0.3	FEET			Depth of the YSI sonde redox potential probe, feet
pHPBFS	7.82	std units		FIU Soil/Sediment Biogeochemistry Laboratory	pH in benthic periphyton as measured in 1:1 (gram wet soil: g distilled de-ionized water) slurry (FIU Soil/Sediment Biogeochemistry Lab)
pHPCFS	7.79	std units		FIU Soil/Sediment Biogeochemistry Laboratory	pH in composite epiphytic and floating periphyton as measured in 1:1 (gram wet soil: g de-ionized distilled water) soil slurry (FIU Soil/Sediment Biogeochemistry Lab)
pHSDFS	7.73	std units		FIU Soil/Sediment Biogeochemistry Laboratory	ex situ soil pH, std units, as measured in 1:1 (gram wet weight soil:gram de-ionized distilled water) soil slurry (FIU Soil/Sediment Biogeochemistry Laboratory)
SO4SWEA	0.024	mg/L	J,Q-2		Sulfate in surface water, mg/L (EPA SESD); MRL=0.02 mg/L
SRPSWFB	0.9	ug/L	U,MDL-U	FIU nutrient analysis laboratory	Soluble Reactive Phosphorus in surface water,ug/L (FIU Nutrient Analysis Lab)
TCPBFS	190	mg/g		FIU Soil/Sediment Biogeochemistry Laboratory	Total Carbon in benthic periphyton, mg per gram, dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
TCPCFS	230	mg/g		FIU Soil/Sediment Biogeochemistry Laboratory	Total Carbon in combined floating and epiphytic periphyton, mg per gram, dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
TCSDFS	170	mg/g		FIU Soil/Sediment Biogeochemistry Laboratory	Total Carbon in soil, mg per gram dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
TEMP	27.67	C			in situ surface water temperature, YSI sonde, degrees C
THGFSFC	14	ng/g		FIU mercury analytical laboratory	Total Mercury in mosquitofish (Gambusia affinis), ug/kg (FIU Mercury Lab); MDL = 3.2 ug/kg; MRL = 9.6 ug/kg; reported as wet weight, composite of up to seven fish
THGPBFC	20	ng/g		FIU mercury analytical laboratory	Total Mercury in benthic periphyton, ng/g (FIU Mercury Lab)
THGPCFC	8.6	ng/g		FIU mercury analytical laboratory	Total Mercury in composite epiphytic and floating periphyton, ng/g (FIU Mercury Lab)
THGSDFC	75	ng/g		FIU mercury analytical laboratory	Total Mercury in soil, ng/g (FIU Mercury Lab), MDL = 2.4 ng/g, MRL = 7.2 ng/g
THGSWFC	0.65	ng/L	U,J,QC-1,B-4	FIU mercury analytical laboratory	Total Mercury in surface water, ng/L (FIU Mercury Lab); MDL = 0.2 ng/L; PQL = 0.5 ng/L
TNPBFS	10	mg/g		FIU Soil/Sediment Biogeochemistry Laboratory	Total Nitrogen in benthic periphyton, mg per g, dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
TNPCFS	11	mg/g		FIU Soil/Sediment Biogeochemistry Laboratory	Total Nitrogen in composite floating and epiphytic periphyton, mg per g, dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
TNSDFS	10	mg/g		FIU Soil/Sediment Biogeochemistry Laboratory	Total Nitrogen in soil, mg per g dry weight (FIU Soil/Sediment Biogeochemistry Laboratory)
TNSWFB	0.47	mg/L		FIU nutrient analysis laboratory	Total Nitrogen in surface water, mg/L (FIU Nutrient Analysis Lab)
TOCSWEA	11	mg/L			Total organic carbon in surface water, mg/L (EPA SESD)
TPPBFB	150	ug/g		FIU nutrient analysis laboratory	Total Phosphorus in benthic periphyton, ug/g dry weight (FIU Nutrient Analysis Lab)
TPPCFB	75	ug/g	A	FIU nutrient analysis laboratory	Total Phosphorus in composite floating and epiphytic periphyton, ug/g dry weight (FIU Nutrient Analysis Lab)
TPSDFB	280	ug/g		FIU nutrient analysis laboratory	Total Phosphorus in soil, ug/g (FIU Nutrient Analysis Lab)
TPSWFB	5	ug/L		FIU nutrient analysis laboratory	Total Phosphorus in surface water, ug/L (FIU Nutrient Analysis Laboratory)

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